| SlNo. | Name | From | To | Profile |
| 1 | Dr. Bimalendu Mohanty | 06-Oct-1999 (FN) | 05-Oct-2001 (AN) | |
| 2 | Sri Nalini Mohan Mohanty, IAS (I/c) | 05-Oct-2001 (AN) | 26-Nov-2001 (AN) | |
| 3 | Sri Narendra Kumar Mishra, IAS (Retd.) | 26-Nov-2001 (AN) | 26-Nov-2004 (AN) | |
| 4 | Sri Madhusudan Padhi, IAS (I/c) | 26-Nov-2004 (AN) | 21-Dec-2004 (AN) | |
| 5 | Prof. (Dr.) Sadhu Charan Panda | 22-Dec-2004 (FN) | 09-Mar-2009 (AN) | |
| 6 | Sri Bijoy Chandra Jena, IAS (I/c) | 13-Mar-2009 (FN) | 30-Apr-2009 (AN) | |
| 7 | Sri Satyendra Narayan Tripathy, IAS (I/c) | 01-May-2009 (FN) | 05-Jun-2009 (FN) | |
| 8 | Dr. Mona Sharma, IAS (I/c) | 05-Jun-2009 (AN) | 16-Feb-2010 (AN) | |
| 9 | Prof. Amiya Kumar Pattanayak | 17-Feb-2010 (FN) | Continuing | |